Discussion on the Interpretation of the Word Catalysis Catalyst

The classical S-B “principle”considered by the catalytic academia is inaccuracy. Theoretical analysis can proves that the catalytic cycle does not exist, and the intermediate cannot appear. The fundamental reason leading to the mistake of S-B principle is that the catalyst participates in the catalytic reaction and the basic principle of chemical reaction equilibrium is ignored. Therefore, the S-B principle's interpretation of & lt;Catalysis, Catalyst & gt; does not correspond to the fundamentals of thermodynamics. The interpretation of "Catalysis, Catalyst" possess misleading. The interpretation of & quot; contact action, contact agent & quot; is more reasonable. Catalytic phenomenon is a physical phenomenon, not a chemical phenomenon, the catalyst does not participate in chemical reactions, it is just contact, electron donate-accept cycle, electron orbital repeated deformation - recovery. Chemical Reaction Model Mechanism-CRMM brings confusion and huge losses to the research and production of catalysts.

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The authors declare no conflict of interest.

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The datasets used in this study are openly available at [repository link] and the source code is available on GitHub at [GitHub link].

This work did not receive any external funding.